First year Animation Mentor students do an exercise of putting a simple character rig into poses that express various emotions. This is a collection of some great examples for reference and inspiration.
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Body dynamics.
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Physical strength
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Balance
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Happiness/Excitement
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Devastation
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Exhaustion
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Boredom
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Concern
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Pose from real life sketch - go outside, sketch a person in an interesting pose, and then pose character using this sketch as a reference.